Pd Nanoparticles Immobilized onto Molecular Sieves by Ionic Liquid: Heterogenerous Catalysts for Solvent-free Hydrogenation
Jun Huang, Tao Jiang, Haixiang Gao, Buxing Han*, Zhimin Liu, Weize Wu, Yanhong Chang, Guoying Zhao
The Pd nanoparticles immobilized onto molecular sieves by 1,1,3,3-tetramethylguanidinium lactate were very active and stable catalysts for the solvent-free hydrogenation of olefins. The excellent synergistic effects between nanoparticles, ionic liquid, and the molecular sieve enhance activity, selectivity, and durability of the catalytic system.
Angew. Chem. Int. Ed. 2004, 43, 1397-1399;